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Sunday, 22 February 2015

PROF. SALIH HACINI, ORAN , ALGERIA

 

Salih HACINI
 

SALIH HACINI

Dr. in Organic Chemistry, Prof. at Oran University; Teacher, Researcher, Expert.

Education

Oran University and Aix-Marseille University,Organic Chemistry- Synthesis

EXPERIENCE




Professor

University of Oran
 – 20+
Researcher; Teacher; Laboratory Director; Scientific supervision





Oran University

University
 –  (3 years 7 months)
Research for preparation of "Doctorat d'Etat" in Organic Chemistry





Algeria




Laboratoire de Chimie fine, Dépt. de Chimie, Faculté des Sciences Université d'Oran-Es-Sénia, BP-1524, 31000 Oran, Algérie
.


Salih Hacini, University of Oran, Algeria


Salih HACINI


An Operationally Simple Base-Catalyzed Multi-component Domino Transformation: Stereoselective Preparation of Trisubstituted Alkenes and 1,3-Dienes
作者：Salih Hacini , Cédric Bories ...
来源：[J].Synthesis, 2005, Vol.2005 (13), pp.2151-2156Thieme
摘 要：A versatile and operationally simple base-catalyzed multi-component domino reaction between α,β-unsaturated carbonyl compounds, aldehydes, and alcohols is described, providing a new efficient, and stereoselective one-pot preparation of trisubstituted alkenes and 1,3-dienes.
作者：Salih Hacini , Emmanuelle Charonnet
来源：[J].Synlett, 2002, Vol.2002 (11), pp.1827-1830Thieme
摘 要：A new multi-component transformation between 1,3-dicarbonyls 1, aldehydes 2,and allylic, propargylic or benzylic halides 3 isdescribed. It provides a regio-, chemo- and stereoselective one-potaccess to α,γ-difunctionalized α-ketoestersand amides 4, bearing a quaternary cente...
作者：... Jacques Viala , Salih Hacini , Jean Rodriguez
来源：[J].Synlett, 2007, Vol.2007 (07), pp.1037-1042Thieme
摘 要：A new strategy from simple cyclic β-ketoesters or amides involving a selective three-component reaction and a ring-closing metathesis or a palladium-catalyzed carbocyclization in a sequential fashion to access spiroheterocycles is reported. This ­expedient two-step sequence ...
作者：Salih Hacini , Jérôme Thibonnet
来源：[J].Synlett, 2009, Vol.2009 (10), pp.1597-1600Thieme
摘 要：Oxacycloisomerization of 1-hydroxy-2-propargyl cyclic derivativeswas catalyzed by the first-generation Grubbs catalyst (Grubbs I)and led to good yields of bicyclic dihydrofurans. Tri­cyclicacetals were also obtained from cyclic alkyne diols using the sameexperimental procedure.
作者：Salih Hacini , Jean-Luc Parrain
来源：[J].Tetrahedron Letters, 1997, Vol.38 (19), pp.3395-3398Elsevier
摘 要：β-Trimethylsilyl allenes have been prepared in fair to good yields from allylsilanes by successive dibromocarbene addition and rearrangement of the cyclopropylidenes. In the case of 3,6-bis(trimethylsilyl)cyclohexa-1,4-diene, insertion of dibromocarbene occurs in the silicon...
作者：Salih Hacini , Roselyne Pardo , Maurice Santelli
来源：[J].Tetrahedron Letters, 1979, Vol.20 (47), pp.4553-4556CrossRef
An Operationally Simple Base‐Catalyzed Multi‐Component Domino Transformation: Stereoselective Preparation of Trisubstituted Alkenes and 1,3‐Dienes.
作者：Salih Hacini , Cedric Bories ...
来源：[J].ChemInform, 2005, Vol.36 (51)Wiley
作者：Salih Hacini , Maurice Santelli
来源：[J].Chem. Commun., 2002, pp.644-645RSC
摘 要：The reaction of 1-trimethylsilylbuta-2,3-diene with tin tetrachloride, antimony trichloride or antimony pentachloride gave the corresponding buta-1,3-dien-2-yl halostannane or stibine derivatives; this ligand exchange was extended to other β-allenylsilanes.
Grubbs Catalyst Promoted Oxacycloisomerization: An Easy Route to Bicyclic Dihydrofurans and Tricyclic Acetals
作者：Salih Hacini , Jérôme Thibonnet
来源：[J].Synlett, 2009, Vol.2009 (10), pp.1597-1600CrossRef
作者：Salih Hacini , Emmanuelle Charonnet
来源：[J].Synlett, 2002, Vol.2002 (11), pp.1827-1830CrossRef

PAPERS

ChemInform Abstract: Palladium-Catalyzed Isomerization of 2-Vinylidenehydrofurans to 1,3Dienes and Some Aspects of Their Reactivitymore


ChemInform Abstract: Grubbs′ Catalyst Promoted Oxacycloisomerization: An Easy Route to Bicyclic Dihydrofurans and Tricyclic Acetalsmore


One step synthesis of octalones or indanones by Friedel?Crafts acylationmore


Transmetallation of β-allenyl silanes: efficient synthesis of dienyl chlorostannanes and chlorostibinesElectronic supplementary information (ESI) available: NMR spectra of compounds 1a and 2a. See http://www.rsc.org/suppdata/cc/b1/b111580bmore


Grubbs Catalyst Promoted Oxacycloisomerization: An Easy Route to Bicyclic Dihydrofurans and Tricyclic Acetalsmore


Palladium‐Catalysed Isomerisation of 2‐Vinylidenehydrofurans to 1, 3‐Dienes and Some Aspects of Their Reactivitymore


An operationally simple base-catalyzed multi-component domino transformation: Stereoselective preparation of trisubstituted alkenes and 1, 3-dienesmore


A New Multicomponent Domino Transformation of 1, 3-Dicarbonyl Compounds: One-Pot Regio-, Chemo-and Stereoselective Access to Valuable α, γ-Difunctionalized …more


Prelog-Djerassi lactone. Preparation of the grieco intermediate from (−)-trans-pulegenic acidmore


Preparation of 4‐Arylcyclopentenes by Sequential Diallylation of Arylaldehydes and Ring‐Closing Metathesismore


An efficient synthesis of the Prelog-Djerassi lactone methyl ester from (-)-< i> trans</i>-pulegenic acidmore


A facile route to cyclopentenones by friedel-crafts acylationmore


A general synthesis of β-silylallenes from allylsilanesmore



An Operationally Simple Base-Catalyzed Multi-component Domino Transformation: Stereoselective Preparation of Trisubstituted Alkenes and 1,3-Dienes

Hadjira Habib-Zahmani, Salih Hacini, Cédric Bories, Robert Faure, Jean Rodriguez*

*Université Paul Cézanne (Aix-Marseille III) , UMR-CNRS-6178-SymBio, Equipe RéSo, Réactivité en Synthèse organique, Centre de St Jérôme, boîte D12, 13397 Marseille cedex 20, France, Email: jean.rodriguezuniv.u-3mrs.fr
H. Habib-Zahmani, S. Hacini, C. Bories, Robert Faure, J. Rodriguez, Synthesis, 2005, 2151-2156.
DOI: 10.1055/s-2005-869979


Abstract
A versatile and operationally simple base-catalyzed multi-component domino reaction between α,β-unsaturated carbonyl compounds, aldehydes, and alcohols is described, providing a new efficient, and stereoselective one-pot preparation of trisubstituted alkenes and 1,3-dienes.

see article for more examples
proposed mechanism



algeria


Map of Algeria


map of Algeria


Université d'Oran
University of Oran جــامــــــعة وهـــــــــران
Université d'Oran
http://www.univ-oran.dz/
University of Oran (Arabic: جامعة وهران‎, French: Université d'Oran), or Es Sénia University (Arabic: جامعة السانية), is a university located in western Algeria in the wilaya of Oran. It was established in November 1961 as part of the University of Algiers. On April 13, 1965 was made a separate campus, and on December 20, 1967 it became an independent University. It was the first university established after the independence of Algeria.
Oran University is one of the most important and largest universities in Algeria. It annually graduates thousands of students in all disciplines from all over Algeria and other Arab and foreign countries. The university also provides scientific and pedagogical supervision to many other universities and university centers in western Algeria.




Es Senia Oran




Trois centres de recherche de dimension nationale sont prévus à l'université d'Oran Es-Sénia au titre du Fonds national de la recherche scientifique, ...











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ORAN TRAM

    1. Map of oran algeria
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      oran
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      Oran algeria




      ORAN TRAM





       Algerian Shakshouka

       



       couscous



       
       paella


       

       
       
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    Hôtel Résidence Pomaria
    Soirée du nouvel an 2015
    L'Hôtel Résidence POMARIA (Mansourah ,Tlemcen), organise à l'occasion du nouvel an 2015 un dîner avec soirée musicale (DJ).
    Possibilité.





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